The electrical conductivity of a metal decreases with rise in temperature while that of a semi-conductor increases. Explain.

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asked Dec 9, 2017 in Chemistry by sforrest072 (157,439 points) 60 409 933

 The electrical conductivity of a metal decreases with rise in temperature while that of a semi-conductor increases. Explain.

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answered Dec 9, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 9, 2017 by sforrest072
 
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In metals with increase of temperature, the kernels start vibrating at faster rate and thus offer resistance to the ow of electrons. Hence, conductivity decreases. In case of semi-conductors, with increase of temperature, more electrons can shift from valence band to conduction band. Hence conductivity increases.

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