Maximum covalence of nitrogen is '4' but the heavier elements of group 15 show covalence greater than '4' Why ?

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asked Dec 18, 2017 in Chemistry by sforrest072 (157,439 points) 61 410 941

Maximum covalence of nitrogen is '4' but the heavier elements of group 15 show covalence greater than '4' Why ?

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answered Dec 18, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 18, 2017 by sforrest072
 
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[Hint : Nitrogen is not having vacant d- orbitals in its octet, hence cannot expand its octet, while heavier members have vacant d-orbitals to expand their octet.]

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