(i) The bond angles (O-N-O) are not of the same value in NO2- and NO2+.

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asked Dec 19, 2017 in Chemistry by sforrest072 (157,439 points) 61 410 947

(i) The bond angles (O-N-O) are not of the same value in NO2- and NO2+.
(ii) BiH3 is the strongest reducing agent amongst all the hydrides of group 15 elements.
(iii) Ammonia has greater afnity for protons than phosphine.

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answered Dec 19, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 19, 2017 by sforrest072
 
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[Hint : (i) Due to presence of lone pair of electron on N in NO2-
(ii) Bi-H bond dissociation enthalpy is least and releases hydrogen mosteasily.
(iii) NH3 is stronger Lewis base than PH3.]

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