Electron gain enthalpy of fluorine (F) is less negative than that of chlorine (Cl). Why ?

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asked Dec 19, 2017 in Chemistry by sforrest072 (157,439 points) 60 410 937

Electron gain enthalpy of fluorine (F) is less negative than that of chlorine (Cl). Why ?

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answered Dec 19, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 19, 2017 by sforrest072
 
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[Hint : Due to small size of F atom and compact 2p orbitals there are strong interelectronic repulsions in the relatively smaller 2p orbitals of fluorine. So the incoming electron does experience more repulsion in F than in Cl.]

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