The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids.

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asked Dec 23, 2017 in Chemistry by sforrest072 (157,439 points) 60 409 933

The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.

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answered Dec 23, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 23, 2017 by sforrest072
 
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Lanthanoids primarily show three oxidation states (+2, +3, +4). Among these oxidation
states, +3 state is the most common. Lanthanoids display a limited number of oxidation states because the energy difference between 4f, 5d, and 6s orbitals is quite large. On the other hand, the energy difference between 5f, 6d, and 7s orbitals is very less. Hence, actinoids display a large number of oxidation states. For example, uranium and plutonium display +3, +4, +5, and +6 oxidation states while neptunium displays +3, +4, +5, and +7. The most common oxidation state in case of actinoids is also +3.

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