Question

Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

(i) (CH₃)₂CHCH(Cl)CH₃
(ii) CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
(iii) CH₃CH₂C(CH₃₎2CH_2I
(iv) (CH3)3CCH2CH(Br)C6H5
(v) CH₃CH(CH₃)CH(Br)CH₃
(vi) CH₃C(C₂H₅)₂CH₂Br
(vii) CH₃C(Cl)(C₂H₅)CH₂CH₃
(viii) CH₃CH=C(Cl)CH₂CH(CH₃)₂
(ix) CH₃CH=CHC(Br)(CH₃)2
(x) p-ClC₆H₄CH₂CH(CH₃)2
(xi) m-ClCH₂C₆H₄CH₂C(CH₃)³
(xii) o-Br-C₆H₄CH(CH₃)CH₂CH₃

Answer 1

2−Chloro−3−methylbutane
(Secondary alkyl halide)

3−Chloro−4−methyhexane
(Secondary alkyl halide)

1−Iodo−2, 2 −dimethylbutane
(Primary alkyl halide)

1−Bromo−3, 3−dimethyl−1−phenylbutane
(Secondary benzyl halide)

2−Bromo−3−methylbutane
(Secondary alkyl halide)

1−Bromo−2−ethyl−2−methylbutane
(Primary alkyl halide)

3−Chloro−3−methylpentane
(Tertiary alkyl halide)