Give two reactions that show the acidic nature of phenol.

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asked Dec 26, 2017 in Chemistry by sforrest072 (157,439 points) 63 447 1243

Give two reactions that show the acidic nature of phenol. Compare acidity of phenol with
that of ethanol.

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answered Dec 26, 2017 by mdsamim (213,225 points) 5 10 21
selected Dec 26, 2017 by sforrest072
 
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The acidic nature of phenol can be represented by the following two reactions:
(i) Phenol reacts with sodium to give sodium phenoxide, liberating H2.

(ii)Phenol reacts with sodium hydroxide to give sodium phenoxide and water as byproducts.

The acidity of phenol is more than that of ethanol. This is because after losing a proton, the phenoxide ion undergoes resonance and gets stabilized whereas ethoxide ion does not.

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