Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.

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asked Dec 26, 2017 in Chemistry by sforrest072 (157,439 points) 61 410 949
Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene.

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answered Dec 26, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 26, 2017 by sforrest072
 
Best answer

The mechanism of acid dehydration of ethanol to yield ethene involves the following three
steps:
Step 1:
Protonation of ethanol to form ethyl oxonium ion:

Step 2:
Formation of carbocation (rate determining step):

Step 3:
Elimination of a proton to form ethene:

The acid consumed in step 1 is released in Step 3. After the formation of ethene, it is removed to shift the equilibrium in a forward direction.

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