How are polymers classified on the basis of structure?

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asked Dec 28, 2017 in Chemistry by sforrest072 (157,439 points) 63 452 1325
How are polymers classified on the basis of structure?

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answered Dec 28, 2017 by mdsamim (213,225 points) 5 10 24
selected Dec 28, 2017 by sforrest072
 
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Polymers are classified on the basis of structure as follows:
1. Linear polymers:
These polymers are formed of long straight chains. They can be depicted as:

For e.g., high density polythene (HDP), polyvinyl chloride, etc.
2. Branched chain polymers:
These polymers are basically linear chain polymers with some branches. These polymers are represented as:

For e.g., low density polythene (LDP), amylopectin, etc.

3. Cross-linked or Network polymers:
These polymers have many cross-linking bonds that give rise to a network-like structure. These polymers contain bi-functional and tri-functional monomers and strong covalent bonds between various linear polymer chains. Examples of such polymers include bakelite and melmac

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