(i) Discuss the nature of bonding in metal carbonyls.

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asked Dec 29, 2017 in Chemistry by sforrest072 (157,439 points) 61 410 949

(i) Discuss the nature of bonding in metal carbonyls.
(ii) Draw gure to show the splitting of d orbitals in an octahedral crystal field and write electronic configuration of Ms+ ion when :

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answered Dec 29, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 29, 2017 by sforrest072
 
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(i) The metal carbon bond in metal carbonyls possess both o and x character.
The M – C o bond if formed by the   while M – C - bond if
formed by the donation of a pair of electron from filled d-orbital of metal to
antibonding x* orbital of CO.

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