When quicklime or calcium oxide (CaO) reacts with water, slaked lime [Ca(OH)2] is formed. During this reaction, a large amount of heat is released. So, this reaction is an exothermic reaction.
CaO(s) + H2O(l) ------>Ca(OH)2(aq) +Heat
calcium oxide water calcium hydroxide
(Quicklime) (slaked lime)