Let the amount of energy released during the electron capture process be Q1. The nuclear reaction can be written as:

Let the amount of energy released during the positron capture process be Q2. The nuclear reaction can be written as:


In other words, this means that if β+ emission is energetically allowed, then the electron capture process is necessarily allowed, but not vice versa. This is because the Q-value must be positive for an energetically-allowed nuclear reaction.