
Relation R is symmetric since (1, 2), (2, 1) ∈ R and (1, 3), (3, 1) ∈ R.
But relation R is not transitive as (3, 1), (1, 2) ∈ R, but (3, 2) ∉ R.
Now, if we add any two pairs (3, 2) and (2, 3) (or both) to relation R, then relation R will become transitive.
Hence, the total number of desired relations is one.
The correct answer is A.