The ionic mobility of alkali metal ions in aqueous solution is maximum for

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asked Mar 31, 2018 in Chemistry by paayal (26,720 points) 4 6 11

The ionic mobility of alkali metal ions in aqueous solution is maximum for

(a) K+ 

(b) Rb+

(c) Li+ 

(d) Na+.

1 Answer

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answered Mar 31, 2018 by sanjaydas (61,430 points) 5 7 7
selected Apr 1, 2018 by Vikash Kumar
 
Best answer

(b) : The alkali metal ion exist as hydrated ions M+(H2O) n in the aqueous solution. The degree of hydration, decreases with ionic size as we go down the group. Hence Li+ ion is mostly hydrated e.g. [Li(H2O)6 ]+. Since the mobility of ions is inversely proportional to the size of the their hydrated ions, hence the increasing order of ionic mobility is Li+(Na+ < K+ < Rb+ )

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