In which of the following octahedral complexes of Co (At. no. 27), will the magnitude of Δoct be the highest?

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asked Mar 31, 2018 in Chemistry by paayal (26,720 points) 4 6 11

In which of the following octahedral complexes of Co (At. no. 27), will the magnitude of Δoct be the highest?

(a) [Co(NH3)6]3+ 

(b) [Co(CN)6]3–

(c) [Co(C2O4)3]3– 

(d) [Co(H2O)6]3+

1 Answer

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answered Mar 31, 2018 by sanjaydas (61,430 points) 5 7 7
selected Apr 1, 2018 by Vikash Kumar
 
Best answer

(b) : Strong field ligand such as CN–, usually produce low spin complexes and large crystal field splittings. H2O is a weaker field ligand than NHand C2O42– 

therefore Δoct [Co(H2O)6]3+ < Δoct [Co(C2O4)]3– < [Co(NH3)6]3+
Common ligands in order of increasing crystal field strength are given below :
I < Br < Cl < F< OH < C2O42– < H2O < NH3
< en < NO2< CN

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