What is the meaning of mechanism of reaction?

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asked Jul 18, 2017 in Chemistry by HariOm Vaja (2,713 points) 4 30 136

(& how is H2O2 related to it?)

1 Answer

+1 vote
answered Jul 19, 2017 by Rohit Singh (61,782 points) 35 133 357
selected Jul 21, 2017 by HariOm Vaja
 
Best answer

Reaction mechanism is a sequence of single reaction steps that sum to the overall equation. For example, a possible mechanism for the overall reaction
2A + B  E + F
might involve these three simpler steps:
(1) A + B  C
(2) C + A  D
(3) D  E + F
Adding the steps and canceling common substances gives the overall equation:
A + B + C + A + D  CD + E + F or 2A + B  E + F
A mechanism is a hypothesis about how a reaction occurs; chemists propose a mechanism and then test to see that it fits with the observed rate law.

Key points

  • The reaction mechanism describes the sequence of elementary reactions that must occur to go from reactants to products.

  • Reaction intermediates are formed in one step and then consumed in a later step of the reaction mechanism.

  • The slowest step in the mechanism is called the rate determining or rate-limiting step.

  • The overall reaction rate is determined by the rates of the steps up to (and including) the rate determining step.

The rapid evolution of oxygen gas is produced by the following reaction:

  • 2 H2O2 (aq)        =    2 H2O (l)   +   O2 (g)    +   heat

The decomposition of hydrogen peroxide in the presence of iodide ion occurs in two steps:

  • H2O2  (aq)   +    I-  (aq)    =    H2O  (l)   +   OI-  (aq)
  • H2O2  (aq)   +   OI-  (aq)    =    H2O  (l)   +   O2  (g)   +   I-  (aq)

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