Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?

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asked Oct 13, 2017 in Chemistry by jisu zahaan (28,760 points) 28 435 1073

Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens? 

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answered Oct 13, 2017 by sforrest072 (157,439 points) 63 448 1260

While testing the Lassaigne’s extract for the presence of halogens, it is first boiled with dilute nitric acid. This is done to decompose NaCN to HCN and Na2S to H2S and to expel these gases. That is, if any nitrogen and sulphur are present in the form of NaCN and Na2S, then they are removed. The chemical equations involved in the reaction are represented as  

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