Actinoid contraction is greater from element to element than lanthanoid contraction. Why?

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asked Dec 25, 2017 in Chemistry by sforrest072 (157,439 points) 60 410 937
Actinoid contraction is greater from element to element than lanthanoid contraction. Why?

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answered Dec 25, 2017 by mdsamim (213,225 points) 5 10 15
selected Dec 25, 2017 by sforrest072
 
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In actinoids, 5f orbitals are filled. These 5f orbitals have a poorer shielding effect than 4f orbitals (in lanthanoids). Thus, the effective nuclear charge experienced by electrons in valence shells in case of actinoids is much more that that experienced by lanthanoids. Hence, the size contraction in actinoids is greater as compared to that in lanthanoids.

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