The feasible region determined by the constraints, x + y ≤ 4, x ≥ 0, y ≥ 0, is as follows.

The corner points of the feasible region are O (0, 0), A (4, 0), and B (0, 4). The values of Z at these points are as follows.

Therefore, the maximum value of Z is 16 at the point B (0, 4).