For the reaction, 2Cl(g) → Cl2(g), what are the signs of ∆H and ∆S ?

+1 vote
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asked Oct 6, 2017 in Chemistry by jisu zahaan (28,760 points) 28 439 1115
edited Oct 6, 2017 by jisu zahaan

For the reaction, 

2Cl(g) → Cl2(g), what are the signs of ∆H and ∆S ? 

1 Answer

+1 vote
answered Oct 6, 2017 by sforrest072 (157,439 points) 63 452 1325
selected Oct 6, 2017 by sanjeev
 
Best answer

∆H and ∆S are negative 

The given reaction represents the formation of chlorine molecule from chlorine atoms. 

Here, bond formation is taking place. Therefore, energy is being released. Hence, ∆H is negative. 

Also, two moles of atoms have more randomness than one mole of a molecule. Since spontaneity is decreased, ∆S is negative for the given reaction. 

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