(i) 0.003MHCl:

Since HCl is completely ionized,

Now,

Hence, the pH of the solution is 2.52.
(ii) 0.005MNaOH:

Hence, the pH of the solution is 11.70.
(iii) 0.002 HBr:

Hence, the pH of the solution is 2.69.
(iv) 0.002 M KOH:

Hence, the pH of the solution is 11.31.