(i) 0.003MHCl:
Since HCl is completely ionized,
Now,
Hence, the pH of the solution is 2.52.
(ii) 0.005MNaOH:
Hence, the pH of the solution is 11.70.
(iii) 0.002 HBr:
Hence, the pH of the solution is 2.69.
(iv) 0.002 M KOH:
Hence, the pH of the solution is 11.31.